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antimony pentafluoride : ウィキペディア英語版
antimony pentafluoride

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Antimony pentafluoride is the inorganic compound with the formula SbF5. This colourless, viscous liquid is a valuable Lewis acid and a component of the superacid fluoroantimonic acid, the strongest known acid. It is notable for its Lewis acidity and its ability to react with almost all known compounds.〔Olah, G. A.; Prakash, G. K. S.; Wang, Q.; Li, X.-y."Antimony(V) Fluoride" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. .〕
==Preparation==
Antimony pentafluoride is prepared by the reaction of antimony pentachloride with anhydrous hydrogen fluoride:〔Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf "Antimony and Antimony Compounds" in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. 〕
:SbCl5 + 5 HF → SbF5 + 5 HCl
It can also be prepared from antimony trifluoride and fluorine.〔Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 200.〕

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